The correct option is that all four pairs are accurately aligned with the United Nations’ proclamations regarding designated International Years. These designations play a crucial role in raising global awareness and promoting specific issues, which reflects the UN's emphasis on sustainable development, peace, and scientific advancement. Understanding such designations is vital for UPSC Prelims as it encompasses international relations, environmental policy, and the role of global governance in setting agendas for sustainable futures, aligning with the broader themes of contemporary issues in India and the world.